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Organoborohydride-catalyzed Chichibabin-type C4-position alkylation of pyridines with alkenes assisted by organoboranes

The first NaBEt(3)H-catalyzed intermolecular Chichibabin-type alkylation of pyridine and its derivatives with alkenes as the latent nucleophiles is presented with the assistance of BEt(3), and a series of branched C4-alkylation pyridines, even highly congested all-carbon quaternary center-containing...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Li, Runhan, Guan, Wei, Li, Yanfei, Li, Xiaohong, Yin, Jianjun, Zhang, Ge, Zhang, Qian, Xiong, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162492/
https://www.ncbi.nlm.nih.gov/pubmed/34094401
http://dx.doi.org/10.1039/d0sc04808a