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The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes

In the past the formyloxyl radical, HC(O)O˙, had only been rarely experimentally observed, and those studies were theoretical-spectroscopic in the context of electronic structure. The absence of a convenient method for the preparation of the formyloxyl radical has precluded investigations into its r...

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Detalles Bibliográficos
Autores principales: Somekh, Miriam, Iron, Mark A., Khenkin, Alexander M., Neumann, Ronny
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162753/
https://www.ncbi.nlm.nih.gov/pubmed/34094405
http://dx.doi.org/10.1039/d0sc04936k