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Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization

Metal hydride complexes find widespread application in catalysis and their properties are often understood on the basis of the available crystal structures. However, some catalytically relevant metal hydrides are only spontaneously formed in situ, cannot be isolated in large quantities or crystallis...

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Detalles Bibliográficos
Autores principales: Salvadori, Enrico, Chiesa, Mario, Buonerba, Antonio, Grassi, Alfonso
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162776/
https://www.ncbi.nlm.nih.gov/pubmed/34123229
http://dx.doi.org/10.1039/d0sc04967k