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Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides

Hydride complexes resulting from the oxidative addition of C–H bonds are intermediates in hydrocarbon activation and functionalization reactions. The discovery of metal systems that enable their direct formation through photoexcitation with visible light could lead to advantageous synthetic methodol...

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Detalles Bibliográficos
Autores principales: Poveda, Dionisio, Vivancos, Ángela, Bautista, Delia, González-Herrero, Pablo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162800/
https://www.ncbi.nlm.nih.gov/pubmed/34123220
http://dx.doi.org/10.1039/d0sc04879h