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Acyclic diaminocarbene-based Thiele, Chichibabin, and Müller hydrocarbons
Thiele, Chichibabin and Müller hydrocarbons are considered as classical Kekulé diradicaloids. Herein we report the synthesis and characterization of acyclic diaminocarbene (ADC)-based Thiele, Chichibabin, and Müller hydrocarbons. The calculated singlet–triplet energy gaps are ΔE(S–T) = −27.96, −3.70...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162802/ https://www.ncbi.nlm.nih.gov/pubmed/34123209 http://dx.doi.org/10.1039/d0sc03622f |