Et(3)SiH + KO(t)Bu provide multiple reactive intermediates that compete in the reactions and rearrangements of benzylnitriles and indolenines

The combination of potassium tert-butoxide and triethylsilane is unusual because it generates multiple different types of reactive intermediates simultaneously that provide access to (i) silyl radical reactions, (ii) hydrogen atom transfer reactions to closed shell molecules and to radicals, (iii) e...

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Detalles Bibliográficos
Autores principales: Smith, Andrew J., Dimitrova, Daniela, Arokianathar, Jude N., Clark, Kenneth F., Poole, Darren L., Leach, Stuart G., Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162870/
https://www.ncbi.nlm.nih.gov/pubmed/34094446
http://dx.doi.org/10.1039/d0sc04244g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162870/
https://www.ncbi.nlm.nih.gov/pubmed/34094446
http://dx.doi.org/10.1039/d0sc04244g

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