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Et(3)SiH + KO(t)Bu provide multiple reactive intermediates that compete in the reactions and rearrangements of benzylnitriles and indolenines
The combination of potassium tert-butoxide and triethylsilane is unusual because it generates multiple different types of reactive intermediates simultaneously that provide access to (i) silyl radical reactions, (ii) hydrogen atom transfer reactions to closed shell molecules and to radicals, (iii) e...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162870/ https://www.ncbi.nlm.nih.gov/pubmed/34094446 http://dx.doi.org/10.1039/d0sc04244g |