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Ruthenium-catalyzed cascade C–H activation/annulation of N-alkoxybenzamides: reaction development and mechanistic insight

A highly selective ruthenium-catalyzed C–H activation/annulation of alkyne-tethered N-alkoxybenzamides has been developed. In this reaction, diverse products from inverse annulation can be obtained in moderate to good yields with high functional group compatibility. Insightful experimental and theor...

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Detalles Bibliográficos
Autores principales: Song, Liangliang, Zhang, Xiaoyong, Tang, Xiao, Van Meervelt, Luc, Van der Eycken, Johan, Harvey, Jeremy N., Van der Eycken, Erik V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162874/
https://www.ncbi.nlm.nih.gov/pubmed/34094402
http://dx.doi.org/10.1039/d0sc04434b