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Oxoiron(v) mediated selective electrochemical oxygenation of unactivated C–H and C[double bond, length as m-dash]C bonds using water as the oxygen source

An efficient electrochemical method for the selective oxidation of C–H bonds of unactivated alkanes (BDE ≤97 kcal mol(−1)) and C[double bond, length as m-dash]C bonds of alkenes using a biomimetic iron complex, [(bTAML)Fe(III)-OH(2)](−), as the redox mediator in an undivided electrochemical cell wit...

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Detalles Bibliográficos
Autores principales: Chandra, Bittu, K. M., Hellan, Pattanayak, Santanu, Gupta, Sayam Sen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162932/
https://www.ncbi.nlm.nih.gov/pubmed/34094416
http://dx.doi.org/10.1039/d0sc03616a