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1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes

The bis(imido) complexes (BDI)Nb(N(t)Bu)(2) and (BDI)Nb(N(t)Bu)(NAr) (BDI = N,N′-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate; Ar = 2,6-diisopropylphenyl) were shown to engage in 1,2-addition and [2 + 2] cycloaddition reactions with a wide variety of substrates. Reaction of the bis(imido)...

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Detalles Bibliográficos
Autores principales: Fostvedt, Jade I., Grant, Lauren N., Kriegel, Benjamin M., Obenhuber, Andreas H., Lohrey, Trevor D., Bergman, Robert G., Arnold, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162998/
https://www.ncbi.nlm.nih.gov/pubmed/34094408
http://dx.doi.org/10.1039/d0sc03489d