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Iron-catalyzed α-C–H functionalization of π-bonds: cross-dehydrogenative coupling and mechanistic insights

The deprotonation of propargylic C–H bonds for subsequent functionalization typically requires stoichiometric metal alkyl or amide reagents. In addition to the undesirable generation of stoichiometric metallic waste, these conditions limit the functional group compatibility and versatility of this f...

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Detalles Bibliográficos
Autores principales: Wang, Yidong, Zhu, Jin, Guo, Rui, Lindberg, Haley, Wang, Yi-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163013/
https://www.ncbi.nlm.nih.gov/pubmed/34094439
http://dx.doi.org/10.1039/d0sc05091a