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Silyloxymethanesulfinate as a sulfoxylate equivalent for the modular synthesis of sulfones and sulfonyl derivatives

An efficient protocol for the modular synthesis of sulfones and sulfonyl derivatives has been developed utilizing sodium tert-butyldimethylsilyloxymethanesulfinate (TBSOMS-Na) as a sulfoxylate (SO(2)(2−)) equivalent. TBSOMS-Na, easily prepared from the commercial reagents Rongalite™ and TBSCl, serve...

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Detalles Bibliográficos
Autores principales: Kim, Dae-Kwon, Um, Hyun-Suk, Park, Hoyoon, Kim, Seonwoo, Choi, Jin, Lee, Chulbom
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163199/
https://www.ncbi.nlm.nih.gov/pubmed/34094489
http://dx.doi.org/10.1039/d0sc02947e