Palladium-catalysed C–F alumination of fluorobenzenes: mechanistic diversity and origin of selectivity

A palladium pre-catalyst, [Pd(PCy(3))(2)] is reported for the efficient and selective C–F alumination of fluorobenzenes with the aluminium(i) reagent [{(ArNCMe)(2)CH}Al] (1, Ar = 2,6-di-iso-propylphenyl). The catalytic protocol results in the transformation of sp(2) C–F bonds to sp(2) C–Al bonds and...

Descripción completa

Detalles Bibliográficos
Autores principales: Rekhroukh, Feriel, Chen, Wenyi, Brown, Ryan K., White, Andrew J. P., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163258/
https://www.ncbi.nlm.nih.gov/pubmed/34094156
http://dx.doi.org/10.1039/d0sc01915a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163258/
https://www.ncbi.nlm.nih.gov/pubmed/34094156
http://dx.doi.org/10.1039/d0sc01915a

Ejemplares similares