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Palladium-catalysed C–F alumination of fluorobenzenes: mechanistic diversity and origin of selectivity
A palladium pre-catalyst, [Pd(PCy(3))(2)] is reported for the efficient and selective C–F alumination of fluorobenzenes with the aluminium(i) reagent [{(ArNCMe)(2)CH}Al] (1, Ar = 2,6-di-iso-propylphenyl). The catalytic protocol results in the transformation of sp(2) C–F bonds to sp(2) C–Al bonds and...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163258/ https://www.ncbi.nlm.nih.gov/pubmed/34094156 http://dx.doi.org/10.1039/d0sc01915a |