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Catalyst control of selectivity in the C–O bond alumination of biomass derived furans

Non-catalysed and catalysed reactions of aluminium reagents with furans, dihydrofurans and dihydropyrans were investigated and lead to ring-expanded products due to the insertion of the aluminium reagent into a C–O bond of the heterocycle. Specifically, the reaction of [{(ArNCMe)(2)CH}Al] (Ar = 2,6-...

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Detalles Bibliográficos
Autores principales: Hooper, Thomas N., Brown, Ryan K., Rekhroukh, Feriel, Garçon, Martí, White, Andrew J. P., Costa, Paulo J., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163288/
https://www.ncbi.nlm.nih.gov/pubmed/34094157
http://dx.doi.org/10.1039/d0sc01918f