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Catalyst control of selectivity in the C–O bond alumination of biomass derived furans
Non-catalysed and catalysed reactions of aluminium reagents with furans, dihydrofurans and dihydropyrans were investigated and lead to ring-expanded products due to the insertion of the aluminium reagent into a C–O bond of the heterocycle. Specifically, the reaction of [{(ArNCMe)(2)CH}Al] (Ar = 2,6-...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163288/ https://www.ncbi.nlm.nih.gov/pubmed/34094157 http://dx.doi.org/10.1039/d0sc01918f |