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A critical analysis of electrospray techniques for the determination of accelerated rates and mechanisms of chemical reactions in droplets

Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS) have been widely used to report evidence that many chemical reactions in micro- and nano-droplets are dramatically accelerated by factors of ∼10(2) to 10(6) relative to macroscale bulk solutions. Despite electrospr...

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Detalles Bibliográficos
Autores principales: Rovelli, Grazia, Jacobs, Michael I., Willis, Megan D., Rapf, Rebecca J., Prophet, Alexander M., Wilson, Kevin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163298/
https://www.ncbi.nlm.nih.gov/pubmed/34094487
http://dx.doi.org/10.1039/d0sc04611f