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The influences of carbon donor ligands on biomimetic multi-iron complexes for N(2) reduction

The active site clusters of nitrogenase enzymes possess the only examples of carbides in biology. These are the only biological FeS clusters that are capable of reducing N(2) to NH(4)(+), implicating the central carbon and its interaction with Fe as important in the mechanism of N(2) reduction. This...

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Detalles Bibliográficos
Autores principales: Nagelski, Alexandra L., Fataftah, Majed S., Bollmeyer, Melissa M., McWilliams, Sean F., MacMillan, Samantha N., Mercado, Brandon Q., Lancaster, Kyle M., Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163302/
https://www.ncbi.nlm.nih.gov/pubmed/34094466
http://dx.doi.org/10.1039/d0sc03447a