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The influences of carbon donor ligands on biomimetic multi-iron complexes for N(2) reduction
The active site clusters of nitrogenase enzymes possess the only examples of carbides in biology. These are the only biological FeS clusters that are capable of reducing N(2) to NH(4)(+), implicating the central carbon and its interaction with Fe as important in the mechanism of N(2) reduction. This...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163302/ https://www.ncbi.nlm.nih.gov/pubmed/34094466 http://dx.doi.org/10.1039/d0sc03447a |