Diverse ring-opening reactions of rhodium η(4)-azaborete complexes

Sequential treatment of [Rh(COE)(2)Cl](2) (COE = cyclooctene) with P(i)Pr(3), alkyne derivatives and (t)BuN[triple bond, length as m-dash]BMes (Mes = 2,4,6-trimethylphenyl) provided functionalized rhodium η(4)-1,2-azaborete complexes of the form (η(4)-azaborete)RhCl(P(i)Pr(3)). The scope of this rea...

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Detalles Bibliográficos
Autores principales: Heß, Merlin, Stennett, Tom E., Fantuzzi, Felipe, Bertermann, Rüdiger, Schock, Marvin, Schäfer, Marius, Thiess, Torsten, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163374/
https://www.ncbi.nlm.nih.gov/pubmed/34123162
http://dx.doi.org/10.1039/d0sc02283g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163374/
https://www.ncbi.nlm.nih.gov/pubmed/34123162
http://dx.doi.org/10.1039/d0sc02283g

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