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The role of neutral donor ligands in the isoselective ring-opening polymerization of rac-β-butyrolactone
Isoenriched poly-3-hydroxybutyrate (P3HB) is a biodegradable material with properties similar to isotactic polypropylene, yet efficient routes to this material are lacking after 50+ years of extensive efforts in catalyst design. In this contribution, a novel lanthanum aminobisphenolate catalyst (1-L...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163396/ https://www.ncbi.nlm.nih.gov/pubmed/34123089 http://dx.doi.org/10.1039/d0sc03507f |