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Ion-molecule reactions catalyzed by a single gold atom

We report that Au atoms within van der Waals complexes serve as catalysts for the first time. This was observed in ionization-induced chemistry of 1,6-hexanediol–Au and 1,8-octanediol–Au complexes formed in superfluid helium nanodroplets, where the addition of Au atom(s) made C(2)H(4)(+) the sole pr...

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Detalles Bibliográficos
Autores principales: Yang, Shengfu, Wu, Hong, Luo, Qiquan, Al Hindawi, Aula M., Sitorus, Berlian, Ellis, Andrew M., Yang, Jinlong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163403/
https://www.ncbi.nlm.nih.gov/pubmed/34123111
http://dx.doi.org/10.1039/d0sc03523h