Photo-triggered hydrogen atom transfer from an iridium hydride complex to unactivated olefins

Many photoactive metal complexes can act as electron donors or acceptors upon photoexcitation, but hydrogen atom transfer (HAT) reactivity is rare. We discovered that a typical representative of a widely used class of iridium hydride complexes acts as an H-atom donor to unactivated olefins upon irra...

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Detalles Bibliográficos
Autores principales: Schreier, Mirjam R., Pfund, Björn, Guo, Xingwei, Wenger, Oliver S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163408/
https://www.ncbi.nlm.nih.gov/pubmed/34123118
http://dx.doi.org/10.1039/d0sc01820a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163408/
https://www.ncbi.nlm.nih.gov/pubmed/34123118
http://dx.doi.org/10.1039/d0sc01820a

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