Cargando…

Direct observation of o-benzyne formation in photochemical hexadehydro-Diels–Alder (hν-HDDA) reactions

Reactive ortho-benzyne derivatives are believed to be the initial products of liquid-phase [4 + 2]-cycloadditions between a 1,3-diyne and an alkyne via what is known as a hexadehydro-Diels–Alder (HDDA) reaction. The UV/VIS spectroscopic observation of o-benzyne derivatives and their photochemical dy...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Xiaonan, Maier, Jan, Wenzel, Michael, Friedrich, Alexandra, Steffen, Andreas, Marder, Todd B., Mitrić, Roland, Brixner, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163437/
https://www.ncbi.nlm.nih.gov/pubmed/34123168
http://dx.doi.org/10.1039/d0sc03184d