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An atropisomeric M(2)L(4) cage mixture displaying guest-induced convergence and strong guest emission in water

Introduction of atropisomeric axes into a bent bispyridine ligand leads to the quantitative formation of a complex mixture of atropisomeric M(2)L(4) cages upon treatment with metal ions. Whereas the isomer ratio of the obtained cage mixture, consisting of up to 42 isomers, is insensitive to temperat...

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Detalles Bibliográficos
Autores principales: Tsutsui, Takahiro, Catti, Lorenzo, Yoza, Kenji, Yoshizawa, Michito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163439/
https://www.ncbi.nlm.nih.gov/pubmed/34123086
http://dx.doi.org/10.1039/d0sc03223a