A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates

The complex [Fe(III)(2)(μ-O(2))(L(3))(4)(S)(2)](4+) (L(3) = 2-(4-thiazolyl)benzimidazole, S = solvent) forms upon reaction of [Fe(II)(L(3))(2)] with H(2)O(2) and is a functional model of peroxo-diiron intermediates invoked during the catalytic cycle of oxidoreductases. The spectroscopic properties o...

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Detalles Bibliográficos
Autores principales: Török, Patrik, Unjaroen, Duenpen, Viktória Csendes, Flóra, Giorgi, Michel, Browne, Wesley R., Kaizer, József
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8168641/
https://www.ncbi.nlm.nih.gov/pubmed/34019062
http://dx.doi.org/10.1039/d1dt01502h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8168641/
https://www.ncbi.nlm.nih.gov/pubmed/34019062
http://dx.doi.org/10.1039/d1dt01502h

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