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Cooperative copper-squaramide catalysis for the enantioselective N–H insertion reaction with sulfoxonium ylides
The first examples of a highly efficient and enantioselective carbene-mediated insertion reaction, from a sulfur ylide, are described. By way of a catalytic asymmetric insertion reaction into N–H bonds from carbonyl sulfoxonium ylides and anilines, using a copper-bifunctional squaramide cooperative...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8171336/ https://www.ncbi.nlm.nih.gov/pubmed/34163835 http://dx.doi.org/10.1039/d1sc00979f |