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Bright luminescent lithium and magnesium carbene complexes

We report on the convenient synthesis of a CNC pincer ligand composed of carbazole and two mesoionic carbenes, as well as the corresponding lithium- and magnesium complexes. Mono-deprotonation affords a rare “naked” amide anion. In contrast to the proligand and its mono-deprotonated form, tri-deprot...

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Detalles Bibliográficos
Autores principales: Pinter, Piermaria, Schüßlbauer, Christoph M., Watt, Fabian A., Dickmann, Nicole, Herbst-Irmer, Regine, Morgenstern, Bernd, Grünwald, Annette, Ullrich, Tobias, Zimmer, Michael, Hohloch, Stephan, Guldi, Dirk M., Munz, Dominik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8171342/
https://www.ncbi.nlm.nih.gov/pubmed/34163830
http://dx.doi.org/10.1039/d1sc00846c