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Is there a photochemical Hammond postulate?

The Hammond postulate is a useful tool for approximating the energy and the structure of transition states. It was designed for use in ground state reactions, and has been applied successfully on many occasions. On the other hand, its usefulness for photochemical reactions is more questionable, as d...

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Detalles Bibliográficos
Autores principales: Bochet, Christian G., Harvey, Freya M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8178980/
https://www.ncbi.nlm.nih.gov/pubmed/34163790
http://dx.doi.org/10.1039/d0sc04370b