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Real-time analysis of methylalumoxane formation

Methylalumoxane (MAO), a perennially useful activator for olefin polymerization precatalysts, is famously intractable to structural elucidation, consisting as it does of a complex mixture of oligomers generated from hydrolysis of pyrophoric trimethylaluminum (TMA). Electrospray ionization mass spect...

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Detalles Bibliográficos
Autores principales: Joshi, Anuj, Zijlstra, Harmen S., Liles, Elena, Concepcion, Carina, Linnolahti, Mikko, McIndoe, J. Scott
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8178985/
https://www.ncbi.nlm.nih.gov/pubmed/34163784
http://dx.doi.org/10.1039/d0sc05075j