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Understanding the unique reactivity patterns of nickel/JoSPOphos manifold in the nickel-catalyzed enantioselective C–H cyclization of imidazoles

The 3d transition metal-catalyzed enantioselective C–H functionalization provides a sustainable strategy for the construction of chiral molecules. A better understanding of the catalytic nature of the reactions and the factors controlling the enantioselectivity is important for rational design of mo...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Biao, Wang, Xin, Messinis, Antonis M., Liu, Xiao-Jun, Kuniyil, Rositha, Chen, De-Zhan, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8178989/
https://www.ncbi.nlm.nih.gov/pubmed/34163805
http://dx.doi.org/10.1039/d0sc04578k