Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with π-single bonding character

Localised singlet diradicals are key intermediates in bond homolysis processes. Generally, these highly reactive species undergo radical–radical coupling reaction immediately after their generation. Therefore, their short-lived character hampers experimental investigations of their nature. In this s...

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Detalles Bibliográficos
Autores principales: Wang, Zhe, Akisaka, Rikuo, Yabumoto, Sohshi, Nakagawa, Tatsuo, Hatano, Sayaka, Abe, Manabu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179019/
https://www.ncbi.nlm.nih.gov/pubmed/34163792
http://dx.doi.org/10.1039/d0sc05311b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179019/
https://www.ncbi.nlm.nih.gov/pubmed/34163792
http://dx.doi.org/10.1039/d0sc05311b

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