Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C–H borylation of heteroarenes

A nontrigonal phosphorus triamide (1, P{N[o-NMe-C(6)H(4)](2)}) is shown to catalyze C–H borylation of electron-rich heteroarenes with pinacolborane (HBpin) in the presence of a mild chloroalkane reagent. C–H borylation proceeds for a range of electron-rich heterocycles including pyrroles, indoles, a...

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Detalles Bibliográficos
Autores principales: Lipshultz, Jeffrey M., Fu, Yue, Liu, Peng, Radosevich, Alexander T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179051/
https://www.ncbi.nlm.nih.gov/pubmed/34163869
http://dx.doi.org/10.1039/d0sc05620k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179051/
https://www.ncbi.nlm.nih.gov/pubmed/34163869
http://dx.doi.org/10.1039/d0sc05620k

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