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Site-selective functionalization of remote aliphatic C–H bonds via C–H metallation

Directing group assistance provided a paradigm for controlling site-selectivity in transition metal-catalyzed C–H functionalization reactions. However, the kinetically and thermodynamically favored formation of 5-membered metallacycles has greatly hampered the selective activation of remote C(sp(3))...

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Detalles Bibliográficos
Autores principales: Zhang, Qi, Shi, Bing-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179183/
https://www.ncbi.nlm.nih.gov/pubmed/34163851
http://dx.doi.org/10.1039/d0sc05944g