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Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers
Installing quaternary stereogenic carbon is an arduous task of contemporary importance in the domain of asymmetric catalysis. To this end, an asymmetric allylic alkylation of α,α-disubstituted aldehydes by using allyl benzoate in the presence of Wilkinson's catalyst [Rh(Cl)(PPh(3))(3)], (R)-BIN...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179253/ https://www.ncbi.nlm.nih.gov/pubmed/34164021 http://dx.doi.org/10.1039/d0sc04959j |