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Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers

Installing quaternary stereogenic carbon is an arduous task of contemporary importance in the domain of asymmetric catalysis. To this end, an asymmetric allylic alkylation of α,α-disubstituted aldehydes by using allyl benzoate in the presence of Wilkinson's catalyst [Rh(Cl)(PPh(3))(3)], (R)-BIN...

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Detalles Bibliográficos
Autores principales:	Pareek, Monika, Sunoj, Raghavan B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179253/ https://www.ncbi.nlm.nih.gov/pubmed/34164021 http://dx.doi.org/10.1039/d0sc04959j

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