Reversible carbon–boron bond formation at platinum centers through σ-BH complexes

A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(I(t)Bu(i)Pr′)(I(t)Bu(i)Pr)][BAr(F)], 1, with tricoordinated boranes HBR(2). X-ray diffraction studies provided structural snapshots of the sequence of reac...

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Detalles Bibliográficos
Autores principales: Ríos, Pablo, Martín-de la Calle, Rocío, Vidossich, Pietro, Fernández-de-Córdova, Francisco José, Lledós, Agustí, Conejero, Salvador
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179255/
https://www.ncbi.nlm.nih.gov/pubmed/34163924
http://dx.doi.org/10.1039/d0sc05522k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179255/
https://www.ncbi.nlm.nih.gov/pubmed/34163924
http://dx.doi.org/10.1039/d0sc05522k

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