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Redox-active benzimidazolium sulfonamides as cationic thiolating reagents for reductive cross-coupling of organic halides

Redox-active benzimidazolium sulfonamides as thiolating reagents have been developed for reductive C–S bond coupling. The IMDN-SO(2)R reagent provides a bench-stable cationic precursor to generate a portfolio of highly active N–S intermediates, which can be successfully applied in cross-electrophili...

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Detalles Bibliográficos
Autores principales: Zhang, Weigang, Huang, Mengjun, Zou, Zhenlei, Wu, Zhengguang, Ni, Shengyang, Kong, Lingyu, Zheng, Youxuan, Wang, Yi, Pan, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179258/
https://www.ncbi.nlm.nih.gov/pubmed/34164018
http://dx.doi.org/10.1039/d0sc06446g