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Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

Metal–organic frameworks are promising materials for applications such as gas capture, separation, and storage, due to their ability to selectively adsorb small molecules. The metal–organic framework Cu(I)-MFU-4l, which contains coordinatively unsaturated copper(i) centers, can engage in backbonding...

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Detalles Bibliográficos
Autores principales: Su, Gregory M., Wang, Han, Barnett, Brandon R., Long, Jeffrey R., Prendergast, David, Drisdell, Walter S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179296/
https://www.ncbi.nlm.nih.gov/pubmed/34163980
http://dx.doi.org/10.1039/d0sc06038k