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Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers
Metal–organic frameworks are promising materials for applications such as gas capture, separation, and storage, due to their ability to selectively adsorb small molecules. The metal–organic framework Cu(I)-MFU-4l, which contains coordinatively unsaturated copper(i) centers, can engage in backbonding...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179296/ https://www.ncbi.nlm.nih.gov/pubmed/34163980 http://dx.doi.org/10.1039/d0sc06038k |