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Molecular engineering enabling reversible transformation between helical and planar conformations by cyclization of alkynes

Molecular engineering enabling reversible transformation between helical and planar conformations is described herein. Starting from easily available 2-(pyridin-2-yl)anilines and alkynes, a one-pot strategy is set up for the synthesis of aza[4]helicenes via two successive rhodium-catalyzed C–H activ...

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Detalles Bibliográficos
Autores principales: Yan, Lipeng, Ma, Weixin, Lan, Jingbo, Cheng, Hu, Bin, Zhengyang, Wu, Di, You, Jingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179297/
https://www.ncbi.nlm.nih.gov/pubmed/34164007
http://dx.doi.org/10.1039/d0sc05844k