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Synthesis and characterization of carbene derivatives of Th@C(3v)(8)-C(82) and U@C(2v)(9)-C(82): exceptional chemical properties induced by strong actinide–carbon cage interaction
Chemical functionalization of endohedral metallofullerenes (EMFs) is essential for the application of these novel carbon materials. Actinide EMFs, a new EMF family member, have presented unique molecular and electronic structures but their chemical properties remain unexplored. Here, for the first t...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179337/ https://www.ncbi.nlm.nih.gov/pubmed/34164015 http://dx.doi.org/10.1039/d0sc06111e |