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Encapsulation of tricopper cluster in a synthetic cryptand enables facile redox processes from Cu(I)Cu(I)Cu(I) to Cu(II)Cu(II)Cu(II) states
One-pot reaction of tris(2-aminoethyl)amine (TREN), [Cu(I)(MeCN)(4)]PF(6), and paraformaldehyde affords a mixed-valent [TREN(4)Cu(II)Cu(I)Cu(I)(μ(3)-OH)](PF(6))(3) complex. The macrocyclic azacryptand TREN(4) contains four TREN motifs, three of which provide a bowl-shape binding pocket for the [Cu(3...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179370/ https://www.ncbi.nlm.nih.gov/pubmed/34164067 http://dx.doi.org/10.1039/d0sc05441k |