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Encapsulation of tricopper cluster in a synthetic cryptand enables facile redox processes from Cu(I)Cu(I)Cu(I) to Cu(II)Cu(II)Cu(II) states

One-pot reaction of tris(2-aminoethyl)amine (TREN), [Cu(I)(MeCN)(4)]PF(6), and paraformaldehyde affords a mixed-valent [TREN(4)Cu(II)Cu(I)Cu(I)(μ(3)-OH)](PF(6))(3) complex. The macrocyclic azacryptand TREN(4) contains four TREN motifs, three of which provide a bowl-shape binding pocket for the [Cu(3...

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Detalles Bibliográficos
Autores principales:	Zhang, Weiyao, Moore, Curtis E., Zhang, Shiyu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179370/ https://www.ncbi.nlm.nih.gov/pubmed/34164067 http://dx.doi.org/10.1039/d0sc05441k

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