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Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst
Since the early Hückel molecular orbital (HMO) calculations in 1950, it has been well known that the odd alternant hydrocarbon (OAH), the phenalenyl (PLY) system, can exist in three redox states: closed shell cation (12π e(−)), mono-reduced open shell neutral radical (13π e(−)) and doubly reduced cl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179390/ https://www.ncbi.nlm.nih.gov/pubmed/34164073 http://dx.doi.org/10.1039/d0sc05972b |