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Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
The isolable chelating bis(N-heterocyclic silylenyl)-substituted terphenyl ligand [Si(II)(Terp)Si(II)] as well as its bis(phosphine) analogue [P(III)(Terp)P(III)] have been synthesised and fully characterised. Their reaction with Ni(cod)(2) (cod = cycloocta-1,5-diene) affords the corresponding 16 VE...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179395/ https://www.ncbi.nlm.nih.gov/pubmed/34164057 http://dx.doi.org/10.1039/d0sc06471h |