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Synthesis, bonding properties and ether activation reactivity of cyclobutadienyl-ligated hybrid uranocenes

A series of hybrid uranocenes consisting of uranium(iv) sandwiched between cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized, structurally characterized and studied computationally. The dimetallic species [(η(4)-Cb′′′′)(η(8)-COT)U(μ:η(2):η(8)-COT)U(THF)(η(4)-Cb′′′′)] (1...

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Detalles Bibliográficos
Autores principales: Tsoureas, Nikolaos, Mansikkamäki, Akseli, Layfield, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179396/
https://www.ncbi.nlm.nih.gov/pubmed/34164062
http://dx.doi.org/10.1039/d0sc05199c