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Synthesis, bonding properties and ether activation reactivity of cyclobutadienyl-ligated hybrid uranocenes
A series of hybrid uranocenes consisting of uranium(iv) sandwiched between cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized, structurally characterized and studied computationally. The dimetallic species [(η(4)-Cb′′′′)(η(8)-COT)U(μ:η(2):η(8)-COT)U(THF)(η(4)-Cb′′′′)] (1...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179396/ https://www.ncbi.nlm.nih.gov/pubmed/34164062 http://dx.doi.org/10.1039/d0sc05199c |