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Ruthenium catalyzed β-selective alkylation of vinylpyridines with aldehydes/ketones via N(2)H(4) mediated deoxygenative couplings
Umpolung (polarity reversal) tactics of aldehydes/ketones have greatly broadened carbonyl chemistry by enabling transformations with electrophilic reagents and deoxygenative functionalizations. Herein, we report the first ruthenium-catalyzed β-selective alkylation of vinylpyridines with both natural...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179402/ https://www.ncbi.nlm.nih.gov/pubmed/34164052 http://dx.doi.org/10.1039/d0sc06586b |