Cargando…
Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
The first iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation is developed in cooperation with Lewis base catalysis. This reaction, catalyzed by cinchonidine and an in situ generated cyclometalated Ir(i)/phosphoramidite complex, makes use of the latent enolate character of an α...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179414/ https://www.ncbi.nlm.nih.gov/pubmed/34164076 http://dx.doi.org/10.1039/d0sc06208a |