Sterically constrained tricyclic phosphine: redox behaviour, reductive and oxidative cleavage of P–C bonds, generation of a dilithium phosphaindole as a promising synthon in phosphine chemistry

The redox behaviour of sterically constrained tricyclic phosphine 3a was investigated by spectroelectrochemistry. The data suggested a highly negative reduction potential with the reversible formation of a dianionic species. Accordingly, 3a reacted with two equivalents of Li/naphthalene by reductive...

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Detalles Bibliográficos
Autores principales: Brand, Alexander, Schulz, Stephen, Hepp, Alexander, Weigand, Jan J., Uhl, Werner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179454/
https://www.ncbi.nlm.nih.gov/pubmed/34163619
http://dx.doi.org/10.1039/d0sc06155g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179454/
https://www.ncbi.nlm.nih.gov/pubmed/34163619
http://dx.doi.org/10.1039/d0sc06155g

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